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Calcination of Hydromagnesite in a Rotary Kiln

Calcination of Hydromagnesite in a Rotary Kiln

Hydromagnesite (brucite) calcination in a rotary kiln primarily yields light-burned magnesia. The core process comprises raw material pretreatment → sealed feeding → segmented calcination in the rotary kiln → rapid cooling → grinding and classification → finished product packaging, with integrated waste-heat recovery and environmental control systems to ensure compliance with indices and product reactivity.


Ⅰ. Full-Process Technology


1. Raw Material Pretreatment Section (Control impurities, uniform particle size, reduce moisture)

Coarse crushing → fine crushing → screening: Raw ore is coarsely crushed by a jaw crusher to 30–50 mm, then shaped and further crushed to 10–30 mm by a hammer crusher; vibration screening ensures uniform particle size.


Impurity removal and purification: Remove red veins and waste rock, and wash with water to remove clay; for high-silica/iron feedstock, magnetic separation is applied to remove iron and enhance purity; alternatively, wet ball milling combined with carbonation can be used for impurity removal.


2. Sealed Feeding Section (Prevent air leakage, ensure stable metering)


Belt-scale conveyor → sealed screw feeder → kiln head sealed hopper, achieving slightly positive-pressure feeding to prevent cold air ingress, which could disrupt the temperature field inside the kiln.


3. Rotary Kiln Calcination Section (Core section, five-zone temperature control)

Section


Temperature range


Key Role


Critical Control Points


Preheating Section


200-400℃

Remove free water and vent   adsorbed gas
  

Heating rate ≤ 10°C/min, to   prevent cracking
  

Pre-decomposition Section


600-700℃

Mg(OH)₂ begins to decompose

Releases H₂O, primarily through   decomposition for energy storage
  

Main Section

700-780℃

Main reaction: Mg (OH)2→MgO+H2O↑

Temperature accuracy of ±10°C   ensures complete decomposition


Homogenization and Stabilization   Section

780-850℃

Grain growth, stabilization   activity

Stay for at least 15 minutes to   prevent overheating

Pre-cooling Section
  

500-600℃

Cooling, preserving activity


Rapid cooling to inhibit grain   growth
  



4. Rapid cooling section (activation locking)

Discharge from kiln head → single-cylinder cooler; rapid cooling below 100℃ to prevent activity loss and pulverization.

Waste-heat recovery: cooling hot air is recycled for preheating in calcination, saving 15%–20% energy.


5. Post-processing and packaging (quality enhancement)


Milling and classification: ball mill / vertical mill to 325 mesh–5 μm (based on customer particle-size requirements); air classification controls particle size D50.


Inspection and packaging: measure MgO content, activity, and whiteness; pack in moisture-proof lined bags to prevent moisture absorption.


II. Key process parameters and control points:

Feed particle size: powder 100–325 mesh, lump 10–30 mm.

Decomposition temperature: 700–780℃ (core range for light calcination).


Atmosphere: Slightly oxidizing, O₂ ≥ 5%, to avoid reduction causing iron contamination.

Kiln speed and slope: Rotational speed 1–3 r/min, slope 2%–4%, matched to material residence time.


III.  Environmental protection and compliance highlights:

Dust control: Baghouse dust collectors at kiln head and kiln tail, emission ≤ 30 mg/m³.

Desulfurization and denitrification: Gas-fired desulfurization tower + SCR, SO₂/NOₓ compliant; natural gas does not require treatment.

Noise: Soundproof enclosures installed on equipment, boundary noise ≤ 60 dB(A).

Problem
 

Reason

Strategy
  

Forming rings/Forming a   crust
  

Uneven particle size, high   moisture content, and excessive temperature


Uniform particle size,   drying, temperature control ≤850°C, kiln cleaning


Insufficient activity

Temperature too low, insufficient   dwell time


Heat to 750–780°C and   extend the dwell time


Over-firing, powdering
  

Temperature too high, slow cooling


Temperature control, rapid   cooling


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